Is there anything stopping IRS from recharacterizing the activity of a rental property s-corp s/h? for purposes of calculating QBI?"
No, IRS has authority to recharacterize distributions into wages subject to FICA( Joeseph Radike vs US(CA-7 895 F2d 1196).
In this case they could argue that a reasonable salary would be the cost of hiring a Property Manager who typcially may charge 8-10% of gross rents.
Rather than expose your client to the risk of recharacterization with subsequent employment tax and loss of QBI, I would look into converting the S corp to an LLC(or SMLCC) where the statutory ground is much firmer and generally a much better choice for holding rental proeprties.