I agree, look at the agreement to determine if it was a stock or asset sale.
If it's a stock sale, any shareholder has the right to review income tax returns. The corporation can deny the request if there is no legitimate purpose for the request, but if the brother now owns 100% it's pretty unlikely the corp would deny the request since the brother is probably sending the request to himself.
I assume this was a bit of a handshake deal, so no transition agreement or anything like that and the brother paid the purchase price all up front?
You could consider asking the brother to work it out with the sister.